N,N-Dimethyl-4-[(2-pyridyl)diazenyl]aniline
نویسندگان
چکیده
The title compound, C(13)H(14)N(4), adopts a trans configuration about the azo bond. There is a dihedral angle of 12.18 (7)° between the pyridine and benzene rings and the mean plane of the dimethyl-amino substituent is twisted by 6.1 (2)° relative to the benzene ring. In the crystal, weak inter-molecular C-H⋯N hydrogen bonds result in a zigzag arrangement along [010].
منابع مشابه
Dichloridobis{N,N-diethyl-4-[(pyridin-2-yl-κN)diazenyl]aniline}zinc
In the title complex, [ZnCl(2)(C(15)H(18)N(4))(2)], the Zn(II) cation is coordinated by two N atoms from the pyridine rings of two unidentate N,N-diethyl-4-[(pyridin-2-yl)diazen-yl]aniline ligands and two Cl atoms, resulting in a distorted tetra-hedral geometry. The ligands are mutually transoid with respect to the metal atom. Weak inter-molecular C-H⋯Cl hydrogen bonds and π-π inter-actions, wi...
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In the title complex, [Ni(CH(3)COO)(C(28)H(26)N(4))]ClO(4), the Ni(II) atom is coordinated by two imine N atoms and two pyridine N atoms of the N-[(E)-1-(6-methyl-2-pyrid-yl)methyl-idene]-2-(2-[(E)-1-(6-methyl-2-pyrid-yl)methyl-idene-amino]-pheneth-yl)aniline donor ligand and two O atoms of the acetate ion in a distorted octa-hedral coordination. The average Ni-N and Ni-O bond lengths are 2.131...
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In the title compound, C(16)H(14)N(4)O, there are inter-molecular N-H⋯N hydrogen bonds which may be effective in stabilizing the crystal. The title compound is an important medicament and is used in the synthesis of anti-tumour drugs.
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